Improvement of graphitization of isotropic carbon by Al 2O 3 formed from aluminium chelate compound

• Published in: Journal of the European Ceramic Society Vol. 19; no. 16; pp. 2843 - 2848
• Main Authors: Yu, J.K, Ueno, S, Li, H.X, Hiragushi, K
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 1999
• Subjects: Al 2O 3; carbon; graphitization; microstructure-final; precursors-organic; graphitization; carbon; microstructure-final; Al 2O 3; precursors-organic
• ISSN: 0955-2219; 1873-619X
• DOI: 10.1016/S0955-2219(99)00065-5

For improving the graphitization of isotropic carbon, ethyl acetoacetate aluminium diisopropoxide and aluminium oxide were used as catalysts. Their effect was investigated and the corresponding mechanism was discussed. The results showed that the isotropic carbon was graphitized greatly by the addition of ethyl acetoacetate aluminium diisopropoxide when the heat-treatment temperature was over 1850°C, and slightly by the addition of aluminium oxide at 1900°C. The mechanism is considered to be that the aluminium compound formed from ethyl acetoacetate aluminium diisopropoxide reacted with C to give Al 4C 3 and with increasing temperature the Al 4C 3 decomposed to form Al(g) and C Gr which was graphitized. Additionally, Al-containing gases and CO 2(g) were the reactants of the reaction between aluminium oxide and C. This showed only a little effect on the graphitization of isotropic carbon when the heat-treating temperature was 1900°C. ©