New tricapped thioether derivatives of Co 3(CO) 9( μ-CPh)
μ-Benzylidyne tricobalt nonacarbonyl, Co 3(CO) 9( μ-CPh), reacts readily with sulfur donor ligands. Tridentate ligands 1,3,5-trithiacyclohexane and tris(thiomethyl)methane both replace three carbonyl groups giving capped derivatives. Dimethylsulfide groups also replace carbonyl groups, forming mono-...
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Published in | Journal of organometallic chemistry Vol. 548; no. 2; pp. 263 - 268 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
1997
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Online Access | Get full text |
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Summary: | μ-Benzylidyne tricobalt nonacarbonyl, Co
3(CO)
9(
μ-CPh), reacts readily with sulfur donor ligands. Tridentate ligands 1,3,5-trithiacyclohexane and tris(thiomethyl)methane both replace three carbonyl groups giving capped derivatives. Dimethylsulfide groups also replace carbonyl groups, forming mono-, di- and trisubstituted derivatives. The capping benzylidyne group is in all cases maintained intact. The crystal structures of the cluster compounds with tridentate sulfur ligands were determined. |
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ISSN: | 0022-328X 1872-8561 |
DOI: | 10.1016/S0022-328X(97)00457-9 |