Metallocenic thioketones as two-electron ligands : III . 13 C nmr spectra and structure of a cymantrene derivative with a cymantrenylphenylthioketone ligand

13C NMR spectra of cymantrenylphenylthioketone and a binuclear complex (η 5-C 5H 5)(CO) 2Mn ← SC(Ph)C 5H 4Mn(CO) 3 (I), produced by substitution of the CO ligand in cymantrene by this thioketone, have been studied. A complete X-ray structural investigation of complex I has been performed. It is sug...

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Published inJournal of organometallic chemistry Vol. 221; no. 2; pp. 183 - 191
Main Authors Andrianov, V.G., Struchkov, Yu.T., Petrovskii, P.V., Fedin, E.I., Kursanov, D.N., Dolgova, S.P., Setkina, V.N.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 1981
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Summary:13C NMR spectra of cymantrenylphenylthioketone and a binuclear complex (η 5-C 5H 5)(CO) 2Mn ← SC(Ph)C 5H 4Mn(CO) 3 (I), produced by substitution of the CO ligand in cymantrene by this thioketone, have been studied. A complete X-ray structural investigation of complex I has been performed. It is suggested that in solution both E and Z isomers of complex I are present.
ISSN:0022-328X
1872-8561
DOI:10.1016/S0022-328X(00)89053-1