Osmium L III edge extended X-ray absorption fine-structure studies on the osmium(VIII) oxide-fluorides, OsO 3F 2,K[OsO 3F 3] and Cs 2[O sO 4F 2]
Osmium L III edge extended X-ray absorption fine-structure data have been obtained for the title compounds and refined to give, for OsO 3F 2, d(OsO)1.70 Å and d(OsF) 1.89 and 2.09 Å, for K[OsO 3F 3], d(OsO)1.70 Å and d(OsF)1.92 Å and, for Cs 2[OsO 4F 2], d(OsO) 1.70 Å and d(OsF) 2.05...
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Published in | Journal of fluorine chemistry Vol. 60; no. 1; pp. 13 - 17 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
1993
|
Online Access | Get full text |
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Summary: | Osmium L
III edge extended X-ray absorption fine-structure data have been obtained for the title compounds and refined to give, for OsO
3F
2,
d(OsO)1.70 Å and
d(OsF) 1.89 and 2.09 Å, for K[OsO
3F
3],
d(OsO)1.70 Å and
d(OsF)1.92 Å and, for Cs
2[OsO
4F
2],
d(OsO) 1.70 Å and
d(OsF) 2.05 Å (bond lengths accurate to ±0.02 Å). |
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ISSN: | 0022-1139 1873-3328 |
DOI: | 10.1016/S0022-1139(00)82188-0 |