Osmium L III edge extended X-ray absorption fine-structure studies on the osmium(VIII) oxide-fluorides, OsO 3F 2,K[OsO 3F 3] and Cs 2[O sO 4F 2]

Osmium L III edge extended X-ray absorption fine-structure data have been obtained for the title compounds and refined to give, for OsO 3F 2, d(OsO)1.70 Å and d(OsF)  1.89 and 2.09 Å, for K[OsO 3F 3], d(OsO)1.70 Å and d(OsF)1.92 Å and, for Cs 2[OsO 4F 2], d(OsO)  1.70 Å and d(OsF)  2.05...

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Published inJournal of fluorine chemistry Vol. 60; no. 1; pp. 13 - 17
Main Authors Brewer, Stuart A., Brisdon, Alan K., Holloway, John H., Hope, Eric G., Levason, William, Ogden, J.Steven, Saad, Ahmed K.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 1993
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Summary:Osmium L III edge extended X-ray absorption fine-structure data have been obtained for the title compounds and refined to give, for OsO 3F 2, d(OsO)1.70 Å and d(OsF)  1.89 and 2.09 Å, for K[OsO 3F 3], d(OsO)1.70 Å and d(OsF)1.92 Å and, for Cs 2[OsO 4F 2], d(OsO)  1.70 Å and d(OsF)  2.05 Å (bond lengths accurate to ±0.02 Å).
ISSN:0022-1139
1873-3328
DOI:10.1016/S0022-1139(00)82188-0