Mechanism of CaO reaction with H 2S: Diffusion through CaS product layer

• Published in: Chemical engineering science Vol. 54; no. 15; pp. 3443 - 3453
• Main Authors: Agnihotri, Rajeev, Chauk, Shriniwas S., Mahuli, Suhas K., Fan, Liang-Shih
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 1999
• Subjects: Calcium oxide sulfidation mechanism; Marker experiment; Product layer diffusion; Solid-state diffusion; Marker experiment; Calcium oxide sulfidation mechanism; Product layer diffusion; Solid-state diffusion
• ISSN: 0009-2509; 1873-4405
• DOI: 10.1016/S0009-2509(98)00339-X

Heterogeneous non-catalytic reaction between CaO and H 2S to capture sulfur in coal-fired gasifier is studied in a differential bed flow-through reactor. Particles of CaO (<10 μm) are exposed to simulated fuel gas containing up to 5000 ppm H 2S in the temperature range 700–900°C. The effects of reaction temperature, H 2S concentration, and sorbent surface area on the extent of sulfur capture and conversion of sorbent are determined. The sulfidation reaction is analyzed using grain model with overall reaction rate controlled by chemical reaction at the interface and by diffusion through the product layer. At the later stages of the reaction, diffusion through the product layer is found to be controlling and involves migration of ions through the product layer. Direct experimental evidence is obtained to determine the migratory nature of ions and identify the mobile ionic species, by performing inert marker experiments. Scanning electron micrographs and sulfur mapping of the partially sulfided CaO tablets suggest that S 2- diffuse in towards the CaO/product layer interface with a counter-diffusion of O 2- towards the product layer/gas interface.