Theoretical optical Zeeman patterns for Mn 2+ in an octahedral or tetrahedral crystal field
Optical Zeeman effect measurements are suggested to study the 4T 1 state of the Mn 2+ ion. Zeeman patterns are calculated in the static crystal field model for Mn 2+ at a site with and without inversion symmetry, respectively. In the first case only magnetic dipole transitions are possible, in the l...
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Published in | Solid state communications Vol. 11; no. 9; pp. 1253 - 1256 |
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Main Author | |
Format | Journal Article |
Language | English |
Published |
Elsevier Ltd
1972
|
Online Access | Get full text |
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Summary: | Optical Zeeman effect measurements are suggested to study the
4T
1
state of the Mn
2+ ion. Zeeman patterns are calculated in the static crystal field model for Mn
2+ at a site with and without inversion symmetry, respectively. In the first case only magnetic dipole transitions are possible, in the latter, electric dipole transitions are allowed. The presence of a strong Jahn-Teller effect will change the Zeeman patterns drastically.
Zum Studium des
4T
1
Zustandes des Mn
2+-Ions werden Messungen des optischen Zeeman-Effekts vorgeschlagen. Es werden Zeeman-Spektren berechnet mithilfe des statischen Kristallfeld-Modells für Mn
2+ auf Gitterstellen mit und ohne Inversions-symmetrie. Im ersten Fall sind nur magnetische Dipol Übergänge erlaubt, im zweiten Fall auch elektrische Dipol Übergänge. Das Vorhanden sein eines starken Jahn-Teller Effekts kann das Zeeman-Spektum drastisch ändern. |
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ISSN: | 0038-1098 1879-2766 |
DOI: | 10.1016/0038-1098(72)90836-8 |