Synthesis and structure of a new organolanthanide oxide complex, (CH 3C 5H 4) 3Yb 4(μ-Cl) 6(μ 3-Cl)(μ 4-O)(THF) 3

Reaction of NaCp′ (Cp′ = C 5H 4CH 3) with YbCl 3 and YbOCl in THF results in the formation of a new complex, Cp′ 3Yb 4(μ-Cl) 6(μ 3-Cl)(μ 4-O)(THF) 3 ( 1). The X-ray crystal structure of 1 reveals an oxygen-centered tetrahedral arrangement of ytterbium atoms which has μ-Cl groups bridging each edge a...

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Published inJournal of organometallic chemistry Vol. 503; no. 1; pp. 11 - 13
Main Authors Zhou, Xigeng, Ma, Huaizhu, Wu, Zhongzhi, You, Xiaozeng, Xu, Zheng, Huang, Xiaoying
Format Journal Article
LanguageEnglish
Published Elsevier B.V 1995
Subjects
Ytterbium
Ytterbium
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Summary:Reaction of NaCp′ (Cp′ = C 5H 4CH 3) with YbCl 3 and YbOCl in THF results in the formation of a new complex, Cp′ 3Yb 4(μ-Cl) 6(μ 3-Cl)(μ 4-O)(THF) 3 ( 1). The X-ray crystal structure of 1 reveals an oxygen-centered tetrahedral arrangement of ytterbium atoms which has μ-Cl groups bridging each edge and a μ 3-Cl ligand over the trianglar face composed of Yb atoms with Cp′ groups.
ISSN:0022-328X
1872-8561
DOI:10.1016/0022-328X(95)05502-G