Synthesis and structure of the trinuclear cluster Fe 3(η 4-C 6H 8)(μ-CO) 2(CO) 6(μ 3-S)

Along with the dithiolatodiironhexacarbonyl complex Fe 2(C 6H 8S 2)(CO) 6, μ 3-thio-η 4-cyclohexa-1,3- diene-(Fe 1-di-μ-carbonyl(Fe 1,Fe 2;Fe 1,Fe 3)hexacarbonyltriiron Fe 3(η 4-C 6H 8)(μ-CO) 2(μ 3-S) has been isolated and characterized by an X-ray study from the interaction products of cyclohexa-1,...

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Published inJournal of organometallic chemistry Vol. 401; no. 1; pp. 75 - 80
Main Authors Nekhaev, A.I., Alekseeva, S.D., Kolobkov, B.I., Aleksandrov, G.G., Toshev, M.T., Dustov, H.B.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 1991
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Summary:Along with the dithiolatodiironhexacarbonyl complex Fe 2(C 6H 8S 2)(CO) 6, μ 3-thio-η 4-cyclohexa-1,3- diene-(Fe 1-di-μ-carbonyl(Fe 1,Fe 2;Fe 1,Fe 3)hexacarbonyltriiron Fe 3(η 4-C 6H 8)(μ-CO) 2(μ 3-S) has been isolated and characterized by an X-ray study from the interaction products of cyclohexa-1,3-diene with sulfur and Fe 3(CO) 12.
ISSN:0022-328X
1872-8561
DOI:10.1016/0022-328X(91)86196-W