The interaction of heterocyclic thioamides with triosmium clusters: The X-ray crystal structure of (μ-H)Os 3(CO) 10(μ-SC=NCH 2CH 2S)

Heterocyclic thioamides react with Os 3(CO) 10(MeCN) 2 to yield complexes HOs 3(CO) 10L of the deprotonated thioamide coordinated in the thiolate form via the exocyclic sulphur atom. Decarbonylation yields HOS 3(CO) 9L with L coordinated via both sulphur and nitrogen: these can be desulphurised to y...

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Published inJournal of organometallic chemistry Vol. 253; no. 1; pp. c1 - c4
Main Authors Brodie, A.M., Holden, H.Diane, Lewis, J., Taylor, M.J.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 1983
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Summary:Heterocyclic thioamides react with Os 3(CO) 10(MeCN) 2 to yield complexes HOs 3(CO) 10L of the deprotonated thioamide coordinated in the thiolate form via the exocyclic sulphur atom. Decarbonylation yields HOS 3(CO) 9L with L coordinated via both sulphur and nitrogen: these can be desulphurised to yield sulphur-capped cluster species.
ISSN:0022-328X
1872-8561
DOI:10.1016/0022-328X(83)80114-4