The phase transitions near the melting point of sbCL 3

Antimony trichloride was studied by nuclear quadrupole resonance, dielectric properties, and differential thermal analysis, with a view to confirming two previously reported phase transitions. No evidence was found to support the existence of a transition near 63.5°C. The phase transition near 70°C...

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Bibliographic Details
Published inJournal of magnetic resonance (1969) Vol. 20; no. 2; pp. 286 - 292
Main Authors Brown, R.J.C, Gillies, G.C, Halliwell, R.E, Segel, S
Format Journal Article
LanguageEnglish
Published Elsevier Inc 1975
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Summary:Antimony trichloride was studied by nuclear quadrupole resonance, dielectric properties, and differential thermal analysis, with a view to confirming two previously reported phase transitions. No evidence was found to support the existence of a transition near 63.5°C. The phase transition near 70°C was manifested as a shoulder on the DTA melting endotherm, and as an abrupt narrowing of the NQR linewidth. The dielectric measurements indicate an appreciable conductivity of the solid which leads to electrode polarization.
ISSN:0022-2364
1557-8968
DOI:10.1016/0022-2364(75)90251-6