The phase transitions near the melting point of sbCL 3
Antimony trichloride was studied by nuclear quadrupole resonance, dielectric properties, and differential thermal analysis, with a view to confirming two previously reported phase transitions. No evidence was found to support the existence of a transition near 63.5°C. The phase transition near 70°C...
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Published in | Journal of magnetic resonance (1969) Vol. 20; no. 2; pp. 286 - 292 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier Inc
1975
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Online Access | Get full text |
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Summary: | Antimony trichloride was studied by nuclear quadrupole resonance, dielectric properties, and differential thermal analysis, with a view to confirming two previously reported phase transitions. No evidence was found to support the existence of a transition near 63.5°C. The phase transition near 70°C was manifested as a shoulder on the DTA melting endotherm, and as an abrupt narrowing of the NQR linewidth. The dielectric measurements indicate an appreciable conductivity of the solid which leads to electrode polarization. |
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ISSN: | 0022-2364 1557-8968 |
DOI: | 10.1016/0022-2364(75)90251-6 |