Gold and silver complexes of methylenebis(dialkyldithiocarbamates) and the X-ray structure of CH 2[S 2CN(CH 2Ph) 2] 2

The coordination chemistry of CH 2(S 2CNR 2) 2 for R = Me, Et, n-Bu and benzyl with Au(I), Au(III) and Ag(I) is examined. The single crystal X-ray diffraction study of CH 2[S 2CN(CH 2Ph) 2] 2 is described. Nineteen new complexes are characterized by IR, 1H, 19F, 31P (when appropriate) NMR, elemental...

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Published inInorganica Chimica Acta Vol. 249; no. 1; pp. 69,76 - 73,77
Main Authors Concepción Gimeno, M., Jambrina, Eduardo, Laguna, Antonio, Laguna, Mariano, Murray, Henry H., Terroba, Raquel
Format Journal Article
LanguageEnglish
Published Elsevier B.V 1996
Subjects
Crystal structures
Dithiocarbamato complexes
Gold complexes
Silver complexes
Crystal structures
Dithiocarbamato complexes
Gold complexes
Silver complexes
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Summary:The coordination chemistry of CH 2(S 2CNR 2) 2 for R = Me, Et, n-Bu and benzyl with Au(I), Au(III) and Ag(I) is examined. The single crystal X-ray diffraction study of CH 2[S 2CN(CH 2Ph) 2] 2 is described. Nineteen new complexes are characterized by IR, 1H, 19F, 31P (when appropriate) NMR, elemental analysis, mass spectra (FAB) and conductivity measurements. Neutral and cationic mono- and dinuclear species have been synthesized. The coordination chemistry of CH 2(S 2CNR 2) 2 is via the CS functionality.
ISSN:0020-1693
1873-3255
DOI:10.1016/0020-1693(96)05027-X