Reaction kinetics of [formula omitted] with O 2
The gas phase reactivities of Mo( a 7 S 3, a 5 S 2, a 5 D J, a 5 G J) with O 2 with O 2 in the temperature range 297–620 K are reported. Mo atoms were produced by the photodissociation of Mo(CO) 6 and MoCl 4 and detected by laser-induced fluorescence. The disappearance rates of all states are found...
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| Published in | Chemical physics letters Vol. 235; no. 5; pp. 497 - 502 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
1995
|
| Online Access | Get full text |
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| Summary: | The gas phase reactivities of
Mo(
a
7
S
3,
a
5
S
2,
a
5
D
J,
a
5
G
J)
with O
2 with O
2 in the temperature range 297–620 K are reported. Mo atoms were produced by the photodissociation of Mo(CO)
6 and MoCl
4 and detected by laser-induced fluorescence. The disappearance rates of all states are found to be pressure independent with argon buffer gas. The disappearance rate constants of the
s
1
d
5
a
7
S
3,
a
5
S
2
and
a
5
G
J
states are on the order of the gas kinetic rate constant. The s
2d
4a
5D
J
states are not as reactive and are found to be temperature dependent. Results are discussed in terms of the different electron configurations of the states. |
|---|---|
| ISSN: | 0009-2614 1873-4448 |
| DOI: | 10.1016/0009-2614(95)00165-Z |