Microwave spectrum of the SO 2-H 2S complex

Ten Δ J= 1 rotational transitions for the SO 2-H 2S complex were observed in the 4–12 GHz frequency range using a pulsed-beam Fourier-transform microwave spectrometer. The complex is a near-prolate asymmetric top with 1 2 (B + C) = 1649(6) MHz and B - C = 228(10) MHz. Some of the observed transition...

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Bibliographic Details
Published inChemical physics letters Vol. 132; no. 1; pp. 67 - 68
Main Authors Pauley, D.J., Bumgarner, R.E., Kukolich, S.G.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 1986
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Summary:Ten Δ J= 1 rotational transitions for the SO 2-H 2S complex were observed in the 4–12 GHz frequency range using a pulsed-beam Fourier-transform microwave spectrometer. The complex is a near-prolate asymmetric top with 1 2 (B + C) = 1649(6) MHz and B - C = 228(10) MHz. Some of the observed transitions show inversion or hindered internal rotation splittings. A tentative structure is a non-planar cyclic complex containing two hydrogen bonds from H 2S to the oxygen atoms on SO 2.
ISSN:0009-2614
1873-4448
DOI:10.1016/0009-2614(86)80696-0