Trimethyl 2,2 #8242;,2 #8242; #8242;-[1,3,5-triazine-2,4,6-triyltris(azanediyl)]triacetate

The title compound, C12H18N6O6, was synthesized via nucleophilic substitution by reacting 2,4,6-trichloro-1,3,5-triazine with glycine methyl ester hydrochloride in reflux (dried toluene) under anhydrous atmosphere. Individual molecules self-assemble via strong N—H...O hydrogen bonds into s...

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Published inActa crystallographica. Section E, Structure reports online Vol. 66; no. 12; pp. o3243 - o3244
Main Authors João Rocha, José A. S. Cavaleiro, Verónica de Zea Bermudez, Sérgio M. F. Vilela, Filipe A. Almeida Paz, João P. C. Tom&#233
Format Journal Article
LanguageEnglish
Published International Union of Crystallography 01.12.2010
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Summary:The title compound, C12H18N6O6, was synthesized via nucleophilic substitution by reacting 2,4,6-trichloro-1,3,5-triazine with glycine methyl ester hydrochloride in reflux (dried toluene) under anhydrous atmosphere. Individual molecules self-assemble via strong N—H...O hydrogen bonds into supramolecular double tapes running parallel to the [010] crystallographic direction. The close packing of supramolecular tapes is mediated by geometrical reasons in tandem with a number of weaker N—H...O and C—H...N hydrogen-bonding interactions.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536810047604