Hydrodynamic dispersion of pressure-induced and electroosmotic flow in porous glasses probed by Nuclear Magnetic Resonance
Fluid transport by flow in random porous media is subject to hydrodynamic dispersion. In a series of pulsed field-gradient NMR experiments, we have compared flow induced by pressure gradients on the one hand and by electroosmosis on the other. The media were porous glasses with pore dimensions from...
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Published in | Diffusion fundamentals Vol. 7 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
01.12.2007
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Online Access | Get full text |
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Summary: | Fluid transport by flow in random porous media is subject to hydrodynamic dispersion. In a series of pulsed field-gradient NMR experiments, we have compared flow induced by pressure gradients on the one hand and by electroosmosis on the other. The media were porous glasses with pore dimensions from 1 to 100 μm. With increasing flow rates, a crossover from subdiffusive to superdiffusive mean-squared displacement laws was observed in both cases. This demonstrates the competition between molecular diffusion and convection, and is a typical example of anomalous transport. |
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ISSN: | 1862-4138 1862-4138 |
DOI: | 10.62721/diffusion-fundamentals.7.150 |