Room temperature synthesis of BaTiO 3 nanoparticles using titanium bis(ammonium lactato) dihydroxide

• Published in: Japanese Journal of Applied Physics Vol. 63; no. 9; p. 9
• Main Authors: Yasuhara, Sou, Orio, Akira, Yasui, Shintaro, Hoshina, Takuya
• Format: Journal Article
• Language: English
• Published: 02.09.2024
• ISSN: 0021-4922; 1347-4065
• DOI: 10.35848/1347-4065/ad70c1

Abstract BaTiO 3 , known for its exceptional ferroelectric properties, is extensively applied in multi-layer ceramics capacitors (MLCCs). Achieving reliable, high-performance MLCCs requires sophisticated ceramics processes, notably in synthesizing submicron-order BaTiO 3 powder with a narrow size distribution. Among various synthesis methods explored for submicron-size BaTiO 3 powder, room temperature liquid-phase synthesis is most desirable due to its cost-effectiveness and large batch availability. In this study, we propose a synthesis method for obtaining BaTiO 3 nanopowder at room temperature using titanium bis(ammonium lactato) dihydroxide and Ba(OH) 2 ·8H 2 O as starting materials, reacted in tert-butylamine with NaOH and ethanol. The resulting powder, exhibiting a cubic phase of BaTiO 3 with an average particle size of 35.8 nm, was obtained after a 7-day reaction at room temperature. Characterization involved X-ray diffraction, differential thermal analysis‒thermogravimetry, and scanning electron microscopy. Subsequently, the powder was used to sinter a BaTiO 3 ceramic, whose dielectric performance was then evaluated.