Mononuclear cobalt(III) azido complex containing a tetradentate amine: one pot synthesis, structure and thermal behavior
One hexacoordinated mononuclear complex trans-[Co(L)(N3)2] PF6 (1) [L = N,N′-bis(3-aminopropyl)- 1,2-ethanediamine] is prepared by using one-pot reactions of the building units and characterized. X-ray analysis shows that cobalt center in 1 adopts a distorted octahedral geometry with CoN6 chromophor...
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| Published in | Bangladesh journal of scientific and industrial research Vol. 57; no. 2; pp. 109 - 116 |
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| Main Author | |
| Format | Journal Article |
| Language | English |
| Published |
26.06.2022
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| Online Access | Get full text |
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| Summary: | One hexacoordinated mononuclear complex trans-[Co(L)(N3)2] PF6 (1) [L = N,N′-bis(3-aminopropyl)- 1,2-ethanediamine] is prepared by using one-pot reactions of the building units and characterized. X-ray analysis shows that cobalt center in 1 adopts a distorted octahedral geometry with CoN6 chromophore ligated through four N atoms of tetradentate amine (L) and the two N atoms of terminal azides in mutual trans orientation. In the crystalline state, double N-H…N and multiple N-H…F hydrogen bondings result in 2D sheet structure. The compound has a thermal stability up to 193°C.
Bangladesh J. Sci. Ind. Res. 57(2), 109-116, 2022 |
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| ISSN: | 0304-9809 2224-7157 |
| DOI: | 10.3329/bjsir.v57i2.60407 |