( E )-2-Phenyl-4-styryl-2,3-dihydro-1 H -1,5-benzodiazepine hemihydrate

The unit cell contains eight molecules of the title compound, with half a water molecule per main molecule, C 23 H 20 N 2 ·0.5H 2 O. The seven-membered diazepine ring adopts a twist-boat conformation and makes dihedral angles of 85.08 (7) and 32.79 (7)° with the phenyl and styryl substituents, respe...

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Bibliographic Details
Published inIUCrData Vol. 2; no. 7
Main Authors Loughzail, Mohamed, Adardour, Mohamed, Dahaoui, Slimane, Baouid, Abdesselam
Format Journal Article
LanguageEnglish
Published 28.07.2017
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Summary:The unit cell contains eight molecules of the title compound, with half a water molecule per main molecule, C 23 H 20 N 2 ·0.5H 2 O. The seven-membered diazepine ring adopts a twist-boat conformation and makes dihedral angles of 85.08 (7) and 32.79 (7)° with the phenyl and styryl substituents, respectively. In the crystal, the organic molecules are linked by C—H...N hydrogen bonds into chains running along the b- axis direction. The water molecule, located on a twofold rotation axis, forms hydrogen bridges, connecting two adjacent chains.
ISSN:2414-3146
2414-3146
DOI:10.1107/S2414314617010707