Di-μ-pyridyl-1:2κ 2 N : C 2 ;2:1κ 2 N : C 2 -μ-tetrahydrofuran-κ 2 O : O -bis[bromo(tetrahydrofuran)magnesium(II)] tetrahydrofuran hemisolvate

The title compound, [Mg 2 Br 2 (C 5 H 4 N) 2 (C 4 H 8 O) 3 ]·0.5C 4 H 8 O, contains dimeric associations of Mg atoms bridged by tetrahydrofuran (THF) molecules. The coordination polyhedron of the Mg atom is a slightly distorted MgCNO 2 Br trigonal bipyramid with two THF molecules in the axial positi...

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Published inActa crystallographica. Section E, Structure reports online Vol. 62; no. 5; pp. m1094 - m1096
Main Authors Churakov, Andrei V., Krut'ko, Dmitry P., Borzov, Maxim V., Kirsanov, Roman S., Belov, Sergei A., Howard, Judith A. K.
Format Journal Article
LanguageEnglish
Published 01.05.2006
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Summary:The title compound, [Mg 2 Br 2 (C 5 H 4 N) 2 (C 4 H 8 O) 3 ]·0.5C 4 H 8 O, contains dimeric associations of Mg atoms bridged by tetrahydrofuran (THF) molecules. The coordination polyhedron of the Mg atom is a slightly distorted MgCNO 2 Br trigonal bipyramid with two THF molecules in the axial positions. One O atom occupies a site with symmetry 2.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536806013742