A Room‐Temperature Luminescent AgCF 3 COO Complex Consisting of Cationic Complex Chains and Anionic Guests
Abstract Reaction of p ‐phenylenediacetonitrile ( p ‐phda) with AgCF 3 COO afforded the coordination polymer, {[Ag 2 ( p ‐phda) 2 ] [Ag 4 (CF 3 COO) 6 ]} n ( 1 ), where the 1D cationic [Ag 2 ( p ‐phda) 2 ] 2+ chain acts as host and the anionic [Ag 4 (CF 3 COO) 6 ] 2– as guest molecules occupy the ch...
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| Published in | Zeitschrift für anorganische und allgemeine Chemie (1950) Vol. 642; no. 8; pp. 584 - 589 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
01.05.2016
|
| Online Access | Get full text |
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| Summary: | Abstract
Reaction of
p
‐phenylenediacetonitrile (
p
‐phda) with AgCF
3
COO afforded the coordination polymer, {[Ag
2
(
p
‐phda)
2
] [Ag
4
(CF
3
COO)
6
]}
n
(
1
), where the 1D cationic [Ag
2
(
p
‐phda)
2
]
2+
chain acts as host and the anionic [Ag
4
(CF
3
COO)
6
]
2–
as guest molecules occupy the channel between neighboring host chains. This is a rare crystal example of AgCF
3
COO complex consisting of cationic complex chains and anionic guests. In addition, complex
1
exhibits luminescence at room temperature in solid state. |
|---|---|
| ISSN: | 0044-2313 1521-3749 |
| DOI: | 10.1002/zaac.201600030 |