Low‐Temperature NO x Removal Using Cu‐Hierarchical SAPO‐34 Catalysts with High Hydrothermal Stability

• Published in: ChemCatChem Vol. 15; no. 11
• Main Authors: Silveira De Araujo, Brenda Roberta, Onrubia‐Calvo, Jon Ander, Pétaud, Guillaume, Nieto‐Marquéz, Antonio, Pereda‐Ayo, Beñat, González Velasco, Juan Ramón, Caravaca, Angel, Gil, Sonia
• Format: Journal Article
• Language: English
• Published: 09.06.2023
• ISSN: 1867-3880; 1867-3899
• DOI: 10.1002/cctc.202300071

Abstract Cu‐hierarchical SAPO‐34‐based catalysts are targeted to allow an efficient gas diffusion through mesopores, improving NO x abatement efficiency at low temperature. A downside of mesopores, however, is that they could eventually reduce hydrothermal stability. To demonstrate the potential of novel catalytic systems, the NH 3 ‐SCR catalytic activity of fresh and hydrothermally treated (HT, in air with 10 % H 2 O at 750 °C for 16 h) hierarchical catalysts was evaluated and compared with a Cu‐microporous catalyst. As expected, the catalytic performances of the hydrothermally treated Cu‐hierarchical catalysts did not surpass that of the microporous one at high temperatures. Nevertheless, their NH 3 ‐SCR catalytic activity at low temperature overcame that of the microporous catalyst, which could be assigned to both: the increase of Cu 2+ active sites after HT and the enhanced diffusion of reactants through the mesopores. This reduction of diffusion resistance by the formation of mesopores was further confirmed by the estimated effectiveness factor.