电化学合成乙醇铪的参数优化、表征和热性能分析
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| Published in | 中国有色金属学报：英文版 Vol. 27; no. 3; pp. 694 - 700 |
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| Main Author | |
| Format | Journal Article |
| Language | English |
| Published |
2017
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1003-6326 |
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| Bibliography: | 43-1239/TG hafnium ethoxide; electrochemical synthesis; parameter optimization; characterization; thermal analysis Hafnium ethoxide was synthesized using electrochemical method.Optimization experiments were used to optimizevarious parameters namely Et4NBr concentration(c):0.01?0.06mol/L,solution temperature(t):30?78°C,polar distance(D):2.0?4.0cm and current density(J):100?400A/m2.The electrolytic products obtained under optimum conditions of c=0.04mol/L,t=78°C,D=2.0cm and J=100A/m2were further isolated by vacuum distillation under5kPa.The product was characterized byFourier transform infrared(FT-IR)spectra,nuclear magnetic resonance(NMR)spectra.The results indicated that the product washafnium ethoxide.ICP analysis suggested that the content of hafnium ethoxide in the final product exceeded99.997%.Thermalproperties of the product were analyzed by TG/DTG.The vaporization enthalpy of hafnium ethoxide was found to be79.1kJ/mol.The result confirmed that hafnium ethoxide was suitable for the preparation of hafnium oxide by atomic layer deposition. |
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| ISSN: | 1003-6326 |