铆钉CuGaS2量子点对提高太阳电池光伏性能的研究

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Published in中国科学:材料科学(英文版) Vol. 60; no. 9; pp. 829 - 838
Main Author 赵晋津 刘正浩 唐浩 贾春媚 赵星宇 薛峰 魏丽玉 孔国丽 王晨 刘金喜
Format Journal Article
LanguageEnglish
Published 2017
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Bibliography:CuGaS2; quantum dots; TiO2 nanoparticles; solar cells; photo-anode
10-1236/TB
Jinjin Zhao1,2,3, Zhenghao Liu1,3, Hao Tang4, Chunmei Jia1, Xingyu Zhao1, Feng Xue5, Liyu Wei1,3, Guoli Kong1, Chen Wang1, Jinxi Liu(1. School of Materials Science and Engineering, Department of Engineering Mechanics, Shi)iazhuang Tiedao University, Shi~iazhuang 050043, China; 2. Engineering Research Center of Nano-Geo Materials of Ministry of Education, China University of Geosciences, Wuhan 430074, China; 3. Shenzhen Key Laboratory of Nanobiomechanics, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China; 4. Department of Materials Science and Engineering, University of Washington, Seattle, WA 98195-2120, USA; 5. Hesteel Group Technology Research Institute, Shijiazhuang 050000, China
Ternary Ⅰ–Ⅲ–Ⅵquantum dots(QDs) of chalcopyrite semiconductors exhibit excellent optical properties in solar cells. In this study, ternary chalcopyrite CuGaS2nanocrystals(2–5 nm) were one-pot anchored on TiO2nanoparticles(TiO2@CGS) without any long ligand. The solar cell with TiO2@CuGaS2/N719 has a power conversion efficiency of7.4%, which is 23% higher than that of monosensitized dye solar cell. Anchoring CuGaS2 QDs on semiconductor nanoparticles to form QDs/dye co-sensitized solar cells is a promising and feasible approach to enhance light absorption,charge carrier generation as well as to facilitate electron injection comparing to conventional mono-dye sensitized solar cells.
ISSN:2095-8226
2199-4501