窄带系非富勒烯受体用于有机太阳电池获得超过21 mA cm^-2的短路电流密度
本文设计合成了基于噻吩[3,2b]噻吩稠环受体具有不同末端基团的三个窄带系非富勒烯受体TTIC-M,TTIC和TTIC-F.采用宽带隙聚合物PBDB-T为给体在300–900 nm光谱范围内形成了互补光吸收,基于TTIC-M,TTIC和TTIC-F的光伏器件分别获得了高达9.97%,10.87%和9.51%的效率和高达21 mA cm^-2的短路电流密度....
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Published in | 中国科学:材料科学(英文版) Vol. 60; no. 9; pp. 819 - 828 |
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Main Author | |
Format | Journal Article |
Language | English |
Published |
2017
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Subjects | |
Online Access | Get full text |
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Summary: | 本文设计合成了基于噻吩[3,2b]噻吩稠环受体具有不同末端基团的三个窄带系非富勒烯受体TTIC-M,TTIC和TTIC-F.采用宽带隙聚合物PBDB-T为给体在300–900 nm光谱范围内形成了互补光吸收,基于TTIC-M,TTIC和TTIC-F的光伏器件分别获得了高达9.97%,10.87%和9.51%的效率和高达21 mA cm^-2的短路电流密度. |
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Bibliography: | Huan-Huan Gao,Yanna Sun,Xiangjian Wan,Bin Kan,Xin Ke,Hongtao Zhang,Chenxi Li,Yongsheng Chen(State Key Laboratory of Elemento-Organic Chemistry,Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer Materials,College of Chemistry,Nankai University, Tianjin 300071, China) 10-1236/TB Three low bandgap non-fullerene acceptors based on thieno[3,2-b]thiophene fused core with different ending groups, named TTIC-M, TTIC, TTIC-F were designed and synthesized. Using a wide bandgap polymer PBDB-T as donor to form a complementary absorption in the range of 300–900 nm, high efficencies of 9.97%, 10.87% and 9.51% were achieved for TTIC-M, TTIC and TTFC-F based photovoltaic devices with impressively high short circuit current over21 mA cm^-2. A-D-A type; non-fullerene acceptors; low bandgap; high short circuit current values |
ISSN: | 2095-8226 2199-4501 |