Proton-anion Ion-pair Recognition by a Hexaazatri- phenylene-Hexaurea Receptor
Recognition behavior of a hexaazatriphenylene （HAT） derivative toward different acids in THF solution was investigated through EH NMR, UV-vis and fluorescence spectroscopic experiments, as well as SEM image and semi-empirical calculations, which revealed that this propeller-like HAT receptor could c...
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| Published in | 中国化学：英文版 Vol. 35; no. 4; pp. 392 - 396 |
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| Main Author | |
| Format | Journal Article |
| Language | English |
| Published |
2017
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Recognition behavior of a hexaazatriphenylene （HAT） derivative toward different acids in THF solution was investigated through EH NMR, UV-vis and fluorescence spectroscopic experiments, as well as SEM image and semi-empirical calculations, which revealed that this propeller-like HAT receptor could co-assemble into a layered complex by sandwiching protons and halogen （chloride or bromide） anions synergistically between the receptor molecules. What＇s more, reversible and remarkable color changes visible to the naked eye could be observed, when the halogen acid and base were introduced alternatively. |
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| AbstractList | Recognition behavior of a hexaazatriphenylene （HAT） derivative toward different acids in THF solution was investigated through EH NMR, UV-vis and fluorescence spectroscopic experiments, as well as SEM image and semi-empirical calculations, which revealed that this propeller-like HAT receptor could co-assemble into a layered complex by sandwiching protons and halogen （chloride or bromide） anions synergistically between the receptor molecules. What＇s more, reversible and remarkable color changes visible to the naked eye could be observed, when the halogen acid and base were introduced alternatively. |
| Author | Tianguang Zhan Mengdi Lin Lin Wu Xiang Zhang Liang Zhang Xin Zhao Kangda Zhang |
| AuthorAffiliation | College of Chemistry and Life Science, Zhejiang Normal University, 688 Yingbin Road, Jinhua, Zhejiang 321004, China Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules,Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China School of Chemical Engineering, Hunan Chemical Vocational Technology College, Zhuzhou, Hunan 412000, China Department of Chemistry, Fudan University, Shanghai 200433, China |
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| Notes | ion,pair recognition, halogen acid sensor, hexaazatriphenylene receptor 31-1547/O6 Recognition behavior of a hexaazatriphenylene （HAT） derivative toward different acids in THF solution was investigated through EH NMR, UV-vis and fluorescence spectroscopic experiments, as well as SEM image and semi-empirical calculations, which revealed that this propeller-like HAT receptor could co-assemble into a layered complex by sandwiching protons and halogen （chloride or bromide） anions synergistically between the receptor molecules. What＇s more, reversible and remarkable color changes visible to the naked eye could be observed, when the halogen acid and base were introduced alternatively. |
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| PublicationTitle | 中国化学：英文版 |
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| PublicationYear | 2017 |
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| Snippet | Recognition behavior of a hexaazatriphenylene （HAT） derivative toward different acids in THF solution was investigated through EH NMR, UV-vis and fluorescence... |
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| StartPage | 392 |
| SubjectTerms | THF溶液 半经验计算 受体分子 离子对 紫外-可见吸收光谱 苯基脲 行为识别 质子 |
| Title | Proton-anion Ion-pair Recognition by a Hexaazatri- phenylene-Hexaurea Receptor |
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