Proton-anion Ion-pair Recognition by a Hexaazatri- phenylene-Hexaurea Receptor

Recognition behavior of a hexaazatriphenylene （HAT） derivative toward different acids in THF solution was investigated through EH NMR, UV-vis and fluorescence spectroscopic experiments, as well as SEM image and semi-empirical calculations, which revealed that this propeller-like HAT receptor could c...

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Bibliographic Details
Published in中国化学：英文版 Vol. 35; no. 4; pp. 392 - 396
Main Author Tianguang Zhan Mengdi Lin Lin Wu Xiang Zhang Liang Zhang Xin Zhao Kangda Zhang
Format Journal Article
LanguageEnglish
Published 2017
Subjects
THF溶液
半经验计算
受体分子
离子对
紫外-可见吸收光谱
苯基脲
行为识别
质子
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Summary:Recognition behavior of a hexaazatriphenylene （HAT） derivative toward different acids in THF solution was investigated through EH NMR, UV-vis and fluorescence spectroscopic experiments, as well as SEM image and semi-empirical calculations, which revealed that this propeller-like HAT receptor could co-assemble into a layered complex by sandwiching protons and halogen （chloride or bromide） anions synergistically between the receptor molecules. What＇s more, reversible and remarkable color changes visible to the naked eye could be observed, when the halogen acid and base were introduced alternatively.
Bibliography:ion,pair recognition, halogen acid sensor, hexaazatriphenylene receptor
31-1547/O6
Recognition behavior of a hexaazatriphenylene （HAT） derivative toward different acids in THF solution was investigated through EH NMR, UV-vis and fluorescence spectroscopic experiments, as well as SEM image and semi-empirical calculations, which revealed that this propeller-like HAT receptor could co-assemble into a layered complex by sandwiching protons and halogen （chloride or bromide） anions synergistically between the receptor molecules. What＇s more, reversible and remarkable color changes visible to the naked eye could be observed, when the halogen acid and base were introduced alternatively.
ISSN:1001-604X
1614-7065