TiO2生产中镁和冷却速度对钛物相转变的影响

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Bibliographic Details
Published in中国有色金属学报:英文版 Vol. 26; no. 9; pp. 2518 - 2522
Main Author 王伊杰 文书明 丰奇成 刘建 任伟成
Format Journal Article
LanguageEnglish
Published 2016
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ISSN1003-6326

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Bibliography:X-ray diffraction(XRD) and crystal structure analysis were used to study the effects of Mg content and cooling rate on the titanium phase transformation of three types of titanium slag. The results indicate that in the rapid cooling process, the titanium phase is anosovite, whose chemical formula is MgnTi(3-n)O5(0n1). In the slow cooling process, when the Mg content is high, anosovite transforms into karrooite MgTi2O5 structure; when the Mg content is low, karrooite MgTi2O5 and rutile TiO2 both exist. The stability of karrooite MgTi2O5 is better than that of anosovite MgnTi(3-n)O5. Slow cooling contributes to the doping of Mg into the anosovite crystal and stabilises the anosovite crystal structure.
43-1239/TG
Yi-jie WANG1,2,Shu-ming WEN1,2,Qi-cheng FENG1,2,Jian LIU1,2,Wei-cheng REN2( 1. State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, China; 2. Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, China)
anosovite; karrooite; rutile; crystal structure; stability
ISSN:1003-6326