Structural and Theoretical Studies of a New Cu^I-Cu^I Complex Bearing Bulky Unsymmetrical Benzamidinate Ligand

Density functional theory（DFT） calculations unambiguously verify that there is little or no direct metalmetal bonding in the dinuclear copper（I） benzamidinate complex [Cu2（LRW）2]（2）{LRR=[PhC（NR）（NR＇）]-（R= 2,6-iPr2C6H3, R＇=SiMe3）} with a short Cu-Cu distance[0.24454（4） nm]....

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Published in高等学校化学研究：英文版 no. 1; pp. 112 - 116
Main Author PAN Chengling TANG Guodong CAO Zhi XU Jiqing SHENG Shaoding
Format Journal Article
LanguageEnglish
Published 2015
Subjects
不对称配体
复合轴承
大件
密度泛函理论
甲脒
结构
苯
铜（I）
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Summary:Density functional theory（DFT） calculations unambiguously verify that there is little or no direct metalmetal bonding in the dinuclear copper（I） benzamidinate complex [Cu2（LRW）2]（2）{LRR=[PhC（NR）（NR＇）]-（R= 2,6-iPr2C6H3, R＇=SiMe3）} with a short Cu-Cu distance[0.24454（4） nm].
Bibliography:Copper（I） complex; Cu-Cu interaction; Benzamidinate; N-Ligand; Density functional theory
Density functional theory（DFT） calculations unambiguously verify that there is little or no direct metalmetal bonding in the dinuclear copper（I） benzamidinate complex [Cu2（LRW）2]（2）{LRR=[PhC（NR）（NR＇）]-（R= 2,6-iPr2C6H3, R＇=SiMe3）} with a short Cu-Cu distance[0.24454（4） nm].
22-1183/06
ISSN:1005-9040
2210-3171