The effect of the amount of ammonia on the Cu~0/Cu~＋ ratio of Cu/SiO_2 catalyst for the hydrogenation of dimethyl oxalate to ethylene glycol

The effect of the amount of precipitant ammonia on the Cu0/Cu＋ratio of Cu/Si O2 prepared by the deposition–precipitation method is investigated. Species at different preparation stages, resulted from the amount of ammonia used, are identified by the XRD and FTIR techniques. Chrysocolla together with...

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Bibliographic Details
Published in中国化学快报：英文版 no. 11; pp. 1461 - 1465
Main Author Feng Li Chun-Shan Lu Xiao-Nian Li
Format Journal Article
LanguageEnglish
Published 2014
Subjects
乙二醇
催化剂制备
比率
氢化
氢氧化铜
氨水溶液
草酸二甲酯
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Summary:The effect of the amount of precipitant ammonia on the Cu0/Cu＋ratio of Cu/Si O2 prepared by the deposition–precipitation method is investigated. Species at different preparation stages, resulted from the amount of ammonia used, are identified by the XRD and FTIR techniques. Chrysocolla together with either copper nitrate hydroxide or copper hydroxide coexist in the uncalcined catalysts. Upon calcination, the latter two species are converted to Cu O particles while chrysocolla remains. Following reduction, Cu O is transformed to metallic Cu and chrysocolla is converted to Cu2 O. The value of Cu0/Cu＋ratio can be evaluated using the peak areas in their TPR profiles. Hydrogenation of dimethyl oxalate（DMO） to ethylene glycol（EG） shows that the selectivity of EG depends on the Cu0/Cu＋ratio. Catalyst prepared with the addition of ammonia solution at n（NH3）/n（Cu2＋） = 0.9 for precipitation–deposition gains a more suitable Cu0/Cu＋ratio upon reduction and thus has a higher selectivity for EG.
Bibliography:The effect of the amount of precipitant ammonia on the Cu0/Cu＋ratio of Cu/Si O2 prepared by the deposition–precipitation method is investigated. Species at different preparation stages, resulted from the amount of ammonia used, are identified by the XRD and FTIR techniques. Chrysocolla together with either copper nitrate hydroxide or copper hydroxide coexist in the uncalcined catalysts. Upon calcination, the latter two species are converted to Cu O particles while chrysocolla remains. Following reduction, Cu O is transformed to metallic Cu and chrysocolla is converted to Cu2 O. The value of Cu0/Cu＋ratio can be evaluated using the peak areas in their TPR profiles. Hydrogenation of dimethyl oxalate（DMO） to ethylene glycol（EG） shows that the selectivity of EG depends on the Cu0/Cu＋ratio. Catalyst prepared with the addition of ammonia solution at n（NH3）/n（Cu2＋） = 0.9 for precipitation–deposition gains a more suitable Cu0/Cu＋ratio upon reduction and thus has a higher selectivity for EG.
11-2710/O6
Amount of ammonia Deposition–precipitation Chrysocolla Copper nitrate hydroxide Copper hydroxide DMO hydrogenation
ISSN:1001-8417
1878-5964