Electrocatalytic response of poly（cobalt tetraaminophthalocyanine）/multi-walled carbon nanotubes-Nafion modified electrode toward sulfadiazine in urine
A highly sensitive amperometric sulfadiazine sensor fabricated by electrochemical deposition of poly（cobalt tetraaminophthalocyanine） （poly（Co II TAPc）） on the surface of a multi-walled carbon nanotubes-Nafion （MWCNTs-Nafion） modified electrode is described.This electrode showed a very attractive pe...
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| Published in | 浙江大学学报：B卷英文版 Vol. 13; no. 6; pp. 503 - 510 |
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| Main Author | |
| Format | Journal Article |
| Language | English |
| Published |
2012
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| Online Access | Get full text |
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| Summary: | A highly sensitive amperometric sulfadiazine sensor fabricated by electrochemical deposition of poly（cobalt tetraaminophthalocyanine） （poly（Co II TAPc）） on the surface of a multi-walled carbon nanotubes-Nafion （MWCNTs-Nafion） modified electrode is described.This electrode showed a very attractive performance by combining the advantages of Co II TAPc,MWCNTs,and Nafion.Compared with the bare glassy carbon electrode （GCE） and the MWCNTs-Nafion modified electrode,the electrocatalytic activity of poly（Co II TAPc）-coated MWCNTs-Nafion GCE generated greatly improved electrochemical detections toward sulfadiazine including low oxidation potential,high current responses,and good anti-fouling performance.The oxidation peak currents of sulfadiazine obtained on the new modified electrode increased linearly while increasing the concentration of sulfadiazine from 0.5 to 43.5 μmol/L with the detection limit of 0.17 μmol/L. |
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| Bibliography: | A highly sensitive amperometric sulfadiazine sensor fabricated by electrochemical deposition of poly（cobalt tetraaminophthalocyanine） （poly（Co II TAPc）） on the surface of a multi-walled carbon nanotubes-Nafion （MWCNTs-Nafion） modified electrode is described.This electrode showed a very attractive performance by combining the advantages of Co II TAPc,MWCNTs,and Nafion.Compared with the bare glassy carbon electrode （GCE） and the MWCNTs-Nafion modified electrode,the electrocatalytic activity of poly（Co II TAPc）-coated MWCNTs-Nafion GCE generated greatly improved electrochemical detections toward sulfadiazine including low oxidation potential,high current responses,and good anti-fouling performance.The oxidation peak currents of sulfadiazine obtained on the new modified electrode increased linearly while increasing the concentration of sulfadiazine from 0.5 to 43.5 μmol/L with the detection limit of 0.17 μmol/L. Sulfadiazine; Electrochemical detection; Cobalt tetraaminophthalocyanine; Multi-walled carbon nanotubes Xiao-ping HONG ,Yan ZHU ,Yan-zhen ZHANG （1 Department of Chemistry,Zhejiang University,Hangzhou 310028,China） （2 Department of Chemistry,Zhejiang Sci-Tech University,Hangzhou 310018,China） （3 Department of Stomatology,the Second Affiliated Hospital,School of Medicine,Zhejiang University,Hangzhou 310009,China） 33-1356/Q |
| ISSN: | 1673-1581 1862-1783 |