Electrosynthesis and Characterization of Poly（N-（9-fluorenylmethoxycarbony）-glycine）

High-quality poly（N-（9-fluorenylmethoxycarbony）-glycine） （PFG）, a new kind of soluble polyfluorene deriva- tive, was successfully synthesized electrochemically by direct anodic oxidation of N-（9-fluorenylmethoxycar- bony）-glycine （FG） in boron trifluoride diethyl etherate （BFEE）. The onset oxidation...

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Bibliographic Details
Published in中国化学：英文版 Vol. 30; no. 4; pp. 985 - 991
Main Author 何宇 郭文娟 裴梅山 张广友
Format Journal Article
LanguageEnglish
Published 2012
Subjects
PFG
三氟化硼乙醚
甘氨酸
电化学活性
电合成
聚芴衍生物
蓝色发光材料
表征
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Summary:High-quality poly（N-（9-fluorenylmethoxycarbony）-glycine） （PFG）, a new kind of soluble polyfluorene deriva- tive, was successfully synthesized electrochemically by direct anodic oxidation of N-（9-fluorenylmethoxycar- bony）-glycine （FG） in boron trifluoride diethyl etherate （BFEE）. The onset oxidation potential of FG in BFEE was only 0.6 V vs. Pt, which was much lower than that in acetonitrile ＋0.1 mol/L tetrabutylammonium tetrafluoro- borate （TBATFB）. PFG film obtained from BFEE showed good electrochemical activity and thermal stability. It in- dicates that BFEE is a better medium for the electrosynthesis of PFG film. PFG is highly soluble in common or- ganic solvents, facilitating potential applications as a blue-light-emitting material. Fluorescent spectra revealed that PFG was a good blue-light emitter. Results of FT-IR and IH NMR spectra indicated the polymerization location of N-（9-fluorenylmethoxycarbony）-glycine occurred mainly at C（2） and C（7） positions of the fluorine ring.
Bibliography:High-quality poly（N-（9-fluorenylmethoxycarbony）-glycine） （PFG）, a new kind of soluble polyfluorene deriva- tive, was successfully synthesized electrochemically by direct anodic oxidation of N-（9-fluorenylmethoxycar- bony）-glycine （FG） in boron trifluoride diethyl etherate （BFEE）. The onset oxidation potential of FG in BFEE was only 0.6 V vs. Pt, which was much lower than that in acetonitrile ＋0.1 mol/L tetrabutylammonium tetrafluoro- borate （TBATFB）. PFG film obtained from BFEE showed good electrochemical activity and thermal stability. It in- dicates that BFEE is a better medium for the electrosynthesis of PFG film. PFG is highly soluble in common or- ganic solvents, facilitating potential applications as a blue-light-emitting material. Fluorescent spectra revealed that PFG was a good blue-light emitter. Results of FT-IR and IH NMR spectra indicated the polymerization location of N-（9-fluorenylmethoxycarbony）-glycine occurred mainly at C（2） and C（7） positions of the fluorine ring.
31-1547/O6
electrochemical polymerization, polyfluorene, fluorescence properties, N-（9-fluorenylmethoxycar- bony）-glycine
ISSN:1001-604X
1614-7065