One pot synthesis of monodispersed L-glutathione stabilized gold nanoparticles for the detection of Pb^2＋ ions

Direct mixture of Au^3＋ with glutathione （GSH）, which act as both reduction agents and stabilizers, in aqueous solution gave rise to production of gold nanoparticles （Au NPs） with uniform sizes of around 21 nm. The GSH stabilizer Au NPs in solution show immediate aggregation after addition of 1 mol/...

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Published in中国计算机科学前沿：英文版 Vol. 5; no. 3; pp. 322 - 328
Main Author Xiang MAO Zheng-Ping LI Zhi-Yong TANG
Format Journal Article
LanguageEnglish
Published 2011
Subjects
一锅法合成
单分散
检测
离子反应
稳定剂
谷胱甘肽
金纳米粒子
黄金
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Summary:Direct mixture of Au^3＋ with glutathione （GSH）, which act as both reduction agents and stabilizers, in aqueous solution gave rise to production of gold nanoparticles （Au NPs） with uniform sizes of around 21 nm. The GSH stabilizer Au NPs in solution show immediate aggregation after addition of 1 mol/L NaCI aqueous solution containing Pb^2＋ ions. The Pb^2＋-induced aggregation in Au NP solution is monitored by both colorimetric response and UV-vis spectroscopy. A rather broad linear range （from 0.1 to 30 pmol/L） and low detection limit （0.1 pmol/L） are explored for Au NP sensors used for detection of Pb^2＋ ions. Furthermore, the response of GSH-stabilized Au NPs toward Pb^2＋ ions is specific compared with other possible interferants （Hg^2＋, Mg^2＋, Zn^2＋, Ni^2＋, Cu^2＋, Co^2＋, Ca^2＋, Mn^2＋, Cd^2＋, and Ba^2＋）.
Bibliography:lead（ll） ion, glutathione （GSH）, gold nanoparticle （Au NP）, detection, colorimetric response
Direct mixture of Au^3＋ with glutathione （GSH）, which act as both reduction agents and stabilizers, in aqueous solution gave rise to production of gold nanoparticles （Au NPs） with uniform sizes of around 21 nm. The GSH stabilizer Au NPs in solution show immediate aggregation after addition of 1 mol/L NaCI aqueous solution containing Pb^2＋ ions. The Pb^2＋-induced aggregation in Au NP solution is monitored by both colorimetric response and UV-vis spectroscopy. A rather broad linear range （from 0.1 to 30 pmol/L） and low detection limit （0.1 pmol/L） are explored for Au NP sensors used for detection of Pb^2＋ ions. Furthermore, the response of GSH-stabilized Au NPs toward Pb^2＋ ions is specific compared with other possible interferants （Hg^2＋, Mg^2＋, Zn^2＋, Ni^2＋, Cu^2＋, Co^2＋, Ca^2＋, Mn^2＋, Cd^2＋, and Ba^2＋）.
11-5731/TP
ISSN:1673-7350
1673-7466