Synthesis of polynorbomene with pendant moiety bearing azide and terminal alkyne groups
A powerful approach to the synthesis of an unprecedented polynorbornene with pendant moiety bearing azide and terminal alkyne groups is developed. Two key intermediates, namely, 3-azido-5-（2-（trimethylsilyl）ethynyl） benzyl alcohol and 4-（4-azatricyclo [5.2.1.0^2.6]dec-8-en-4-yl） benzoic acid, were o...
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| Published in | 中国化学快报：英文版 Vol. 22; no. 7; pp. 785 - 788 |
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| Main Author | |
| Format | Journal Article |
| Language | English |
| Published |
2011
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| Subjects | |
| Online Access | Get full text |
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| Abstract | A powerful approach to the synthesis of an unprecedented polynorbornene with pendant moiety bearing azide and terminal alkyne groups is developed. Two key intermediates, namely, 3-azido-5-（2-（trimethylsilyl）ethynyl） benzyl alcohol and 4-（4-azatricyclo [5.2.1.0^2.6]dec-8-en-4-yl） benzoic acid, were optimally synthesized for convergent synthesis of the corresponding monomer. |
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| AbstractList | A powerful approach to the synthesis of an unprecedented polynorbornene with pendant moiety bearing azide and terminal alkyne groups is developed. Two key intermediates, namely, 3-azido-5-（2-（trimethylsilyl）ethynyl） benzyl alcohol and 4-（4-azatricyclo [5.2.1.0^2.6]dec-8-en-4-yl） benzoic acid, were optimally synthesized for convergent synthesis of the corresponding monomer. |
| Author | Ze Zhang Zhi Wei Peng Kun Zeng Fan |
| AuthorAffiliation | School of Biochemical Engineering, Anhui Polytechnic University, Wuhu 241000, China Department of Chemistry, University of Science and Technology of China, Hefei 230026, China |
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| DocumentTitleAlternate | Synthesis of polynorbomene with pendant moiety bearing azide and terminal alkyne groups |
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| Notes | 11-2710/O6 A powerful approach to the synthesis of an unprecedented polynorbornene with pendant moiety bearing azide and terminal alkyne groups is developed. Two key intermediates, namely, 3-azido-5-（2-（trimethylsilyl）ethynyl） benzyl alcohol and 4-（4-azatricyclo [5.2.1.0^2.6]dec-8-en-4-yl） benzoic acid, were optimally synthesized for convergent synthesis of the corresponding monomer. Polynorbomene; Azide; Alkyne; Esterification; Metathesis |
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| PublicationTitle | 中国化学快报：英文版 |
| PublicationTitleAlternate | Chinese Chemical Letters |
| PublicationYear | 2011 |
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| Snippet | A powerful approach to the synthesis of an unprecedented polynorbornene with pendant moiety bearing azide and terminal alkyne groups is developed. Two key... |
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| SubjectTerms | 三甲基硅基 叠氮 合成 基团 挂件 端炔 群体 轴承 |
| Title | Synthesis of polynorbomene with pendant moiety bearing azide and terminal alkyne groups |
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