Synthesis of polynorbomene with pendant moiety bearing azide and terminal alkyne groups

A powerful approach to the synthesis of an unprecedented polynorbornene with pendant moiety bearing azide and terminal alkyne groups is developed. Two key intermediates, namely, 3-azido-5-（2-（trimethylsilyl）ethynyl） benzyl alcohol and 4-（4-azatricyclo [5.2.1.0^2.6]dec-8-en-4-yl） benzoic acid, were o...

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Published in中国化学快报：英文版 Vol. 22; no. 7; pp. 785 - 788
Main Author Ze Zhang Zhi Wei Peng Kun Zeng Fan
Format Journal Article
LanguageEnglish
Published 2011
Subjects
三甲基硅基
叠氮
合成
基团
挂件
端炔
群体
轴承
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Summary:A powerful approach to the synthesis of an unprecedented polynorbornene with pendant moiety bearing azide and terminal alkyne groups is developed. Two key intermediates, namely, 3-azido-5-（2-（trimethylsilyl）ethynyl） benzyl alcohol and 4-（4-azatricyclo [5.2.1.0^2.6]dec-8-en-4-yl） benzoic acid, were optimally synthesized for convergent synthesis of the corresponding monomer.
Bibliography:11-2710/O6
A powerful approach to the synthesis of an unprecedented polynorbornene with pendant moiety bearing azide and terminal alkyne groups is developed. Two key intermediates, namely, 3-azido-5-（2-（trimethylsilyl）ethynyl） benzyl alcohol and 4-（4-azatricyclo [5.2.1.0^2.6]dec-8-en-4-yl） benzoic acid, were optimally synthesized for convergent synthesis of the corresponding monomer.
Polynorbomene; Azide; Alkyne; Esterification; Metathesis
ISSN:1001-8417
1878-5964