Information and Configurational Entropy in Glassy Systems

It is often stated that if one is presented with a snapshot of the positions of the molecules of a glass and one of a liquid, one is unable to tell the difference. Here we argue instead that given several such snapshots taken over a time-interval, even without specifying the times, there is a defini...

Full description

Saved in:
Bibliographic Details
Main Authors Fraenkel, Ittai, Kurchan, Jorge, Levine, Dov
Format Journal Article
LanguageEnglish
Published 07.02.2024
Subjects
Physics - Disordered Systems and Neural Networks
Online AccessGet full text
DOI10.48550/arxiv.2402.05081

Cover

More Information
Summary:It is often stated that if one is presented with a snapshot of the positions of the molecules of a glass and one of a liquid, one is unable to tell the difference. Here we argue instead that given several such snapshots taken over a time-interval, even without specifying the times, there is a definite procedure to assess precisely the level of glassiness: it suffices to concatenate the snapshots side-by-side, and to subject the joint picture to a lossless compression protocol. We argue that the size of the compressed file yields a direct and unambiguous measure of the `vibrational' and `configurational' entropies, and may be used to study the associated glass length scale in or out of equilibrium through the size and frequency of the repeated motifs essential to the compression, a quantity that would diverge at a putative glass transition.
DOI:10.48550/arxiv.2402.05081