Isothermal Annealing of Shocked Zirconium: Stability of the Two-phase $\alpha/\omega$ Microstructure

• Main Authors: Low, Thaddeus Song En, Brown, Donald W, Welk, Brian A, Cerreta, Ellen K, Okasinski, Jon S, Niezgoda, Stephen R
• Format: Journal Article
• Language: English
• Published: 12.11.2014
• Subjects: Physics - Materials Science
• DOI: 10.48550/arxiv.1411.3298

T.S.E. Low, D.W. Brown, B.A. Welk, E.K. Cerreta, J.S. Okasinski, S.R. Niezgoda, Isothermal annealing of shocked zirconium: Stability of the two-phase microstructure, Acta Materialia, Volume 91, 1 June 2015, Pages 101-111 Under high pressure conditions, Zr undergoes a phase transformation from its ambient equilibrium hexagonal close packed $\alpha$ phase to hexagonal $\omega$ phase. Upon returning to ambient conditions, the material displays hysteretic behavior, retaining a significant amount of metastable $\omega$ phase. This study presents an in-situ synchrotron X-ray diffraction analysis of Zr samples shock-loaded to compressive peak stresses of 8 and 10.5 GPa and then annealed at temperatures of 443, 463, 483, and 503K. The evolution of the $\alpha$ phase volume fraction was tracked quantitatively, and the dislocation densities in both phases were tracked qualitatively during annealing. Upon heating, the reverse transformation of $\omega\to\alpha$ does not go to completion, but instead reaches a new metastable state. The initial rate of transformation is faster at higher temperatures. Samples shock-loaded to higher peak pressures experienced higher initial transformation rates and more extensive transformation. Dislocation content in both phases was observed to be high in the as-shocked samples. Annealing the samples reduces the dislocation content in both phases, with the reduction being lesser in the $\omega$ phase, leading to the postulation that transformation from $\omega\to\alpha$ is restricted by the pinning effect of dislocation structures within the $\omega$ phase. Electron backscatter diffraction analysis affirmed that the expected $(0\;0\;0\;1)_\alpha\parallel(1\;0\;\overline{1}\;1)_\omega$ and $[1\;0\;\overline{1}\;0]_\alpha\parallel[1\;1\;\overline{2}\;\overline{3}]_\omega$ orientation relationship is maintained during nucleation and growth of the $\alpha$ phase during the annealing. \end{abstract}