Die Kristallstruktur des η5-C5H5Ru(CO)2(CONH2) [1] / The Crystal Structure of η5-C5H5Ru(CO)2(CONH2) [1]
The crystal structure of the monoclinic η5-C RU(CO) (CONH ) has been determined by X-ray diffraction (space group P1̄ with Z - 4 and a = 1248,3 pm, b = 963,3 pm, c = 845,2 pm, α= 97,35°, β= 106,11°, and γ= 99,32°). The Ru is pseudo-octahedrally coordinated to the η -C ring, the two CO groups and the...
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| Published in | Zeitschrift für Naturforschung. B, A journal of chemical sciences Vol. 34; no. 11; pp. 1487 - 1490 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Verlag der Zeitschrift für Naturforschung
01.11.1979
|
| Subjects | |
| Online Access | Get full text |
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| Abstract | The crystal structure of the monoclinic η5-C
RU(CO)
(CONH
) has been determined by X-ray diffraction (space group P1̄ with Z - 4 and a = 1248,3 pm, b = 963,3 pm, c = 845,2 pm, α= 97,35°, β= 106,11°, and γ= 99,32°). The Ru is pseudo-octahedrally coordinated to the η
-C
ring, the two CO groups and the CONH
ligand with a planar RuC(O)N-moiety. Dimers are formed by N-H···O hydrogen bonds connecting the carbamoyl ligands of two molecules. Further hydrogen bonds link these dimers to form a helical chain. |
|---|---|
| AbstractList | The crystal structure of the monoclinic η5-C
RU(CO)
(CONH
) has been determined by X-ray diffraction (space group P1̄ with Z - 4 and a = 1248,3 pm, b = 963,3 pm, c = 845,2 pm, α= 97,35°, β= 106,11°, and γ= 99,32°). The Ru is pseudo-octahedrally coordinated to the η
-C
ring, the two CO groups and the CONH
ligand with a planar RuC(O)N-moiety. Dimers are formed by N-H···O hydrogen bonds connecting the carbamoyl ligands of two molecules. Further hydrogen bonds link these dimers to form a helical chain. |
| Author | Jungbauer, Anton Wagner, Hubertus Thiele, Gerhard Behrens, Helmut |
| Author_xml | – sequence: 1 givenname: Hubertus surname: Wagner fullname: Wagner, Hubertus organization: Institut für Anorganische Chemie der Universität Erlangen-Nürnberg, Egerlandstraße 1, D-8520 Erlangen – sequence: 2 givenname: Anton surname: Jungbauer fullname: Jungbauer, Anton organization: Institut für Anorganische Chemie der Universität Erlangen-Nürnberg, Egerlandstraße 1, D-8520 Erlangen – sequence: 3 givenname: Gerhard surname: Thiele fullname: Thiele, Gerhard organization: Institut für Anorganische Chemie der Universität Erlangen-Nürnberg, Egerlandstraße 1, D-8520 Erlangen – sequence: 4 givenname: Helmut surname: Behrens fullname: Behrens, Helmut organization: Institut für Anorganische Chemie der Universität Erlangen-Nürnberg, Egerlandstraße 1, D-8520 Erlangen |
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| DOI | 10.1515/znb-1979-1102 |
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| PublicationTitle | Zeitschrift für Naturforschung. B, A journal of chemical sciences |
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| Snippet | The crystal structure of the monoclinic η5-C
RU(CO)
(CONH
) has been determined by X-ray diffraction (space group P1̄ with Z - 4 and a = 1248,3 pm, b = 963,3... |
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| StartPage | 1487 |
| SubjectTerms | Carbamoyl Complex Carbonyl Complex Crystal Structure Ruthenium (+II) Complex η5-Cyclopentadienyl Complex |
| Title | Die Kristallstruktur des η5-C5H5Ru(CO)2(CONH2) [1] / The Crystal Structure of η5-C5H5Ru(CO)2(CONH2) [1] |
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