Die Kristallstruktur des η5-C5H5Ru(CO)2(CONH2) [1] / The Crystal Structure of η5-C5H5Ru(CO)2(CONH2) [1]

The crystal structure of the monoclinic η5-C RU(CO) (CONH ) has been determined by X-ray diffraction (space group P1̄ with Z - 4 and a = 1248,3 pm, b = 963,3 pm, c = 845,2 pm, α= 97,35°, β= 106,11°, and γ= 99,32°). The Ru is pseudo-octahedrally coordinated to the η -C ring, the two CO groups and the...

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Published inZeitschrift für Naturforschung. B, A journal of chemical sciences Vol. 34; no. 11; pp. 1487 - 1490
Main Authors Wagner, Hubertus, Jungbauer, Anton, Thiele, Gerhard, Behrens, Helmut
Format Journal Article
LanguageEnglish
Published Verlag der Zeitschrift für Naturforschung 01.11.1979
Subjects
Carbamoyl Complex
Carbonyl Complex
Crystal Structure
Ruthenium (+II) Complex
η5-Cyclopentadienyl Complex
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Summary:The crystal structure of the monoclinic η5-C RU(CO) (CONH ) has been determined by X-ray diffraction (space group P1̄ with Z - 4 and a = 1248,3 pm, b = 963,3 pm, c = 845,2 pm, α= 97,35°, β= 106,11°, and γ= 99,32°). The Ru is pseudo-octahedrally coordinated to the η -C ring, the two CO groups and the CONH ligand with a planar RuC(O)N-moiety. Dimers are formed by N-H···O hydrogen bonds connecting the carbamoyl ligands of two molecules. Further hydrogen bonds link these dimers to form a helical chain.
ISSN:0932-0776
1865-7117
DOI:10.1515/znb-1979-1102