Darstellung von SCl2F+MF6~ (M = As, Sb) und zusammenfassende Betrachtung der Kationen SClnF3-n+ (n = 0-3) [1] / Preparation of SCl2F+MF6~ (M = As, Sb) and a Comprehensive Discussion of the Cations SClnF3-n+ (n = 0-3) [1]

The preparations and characterizations of compounds SCl MF ~ (M = As, Sb) are reported. They are yellowish hydrolysable solids, with a strong tendency towards symmetrization in solution. The mass spectra data indicate the formation of SCl on thermolysis. The series of SCl -cations (n = 0—3) is now c...

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Published inZeitschrift für Naturforschung. B, A journal of chemical sciences Vol. 44; no. 11; pp. 1343 - 1347
Main Authors Minkwitz, Rolf, Nowicki, Gabriele
Format Journal Article
LanguageEnglish
Published Verlag der Zeitschrift für Naturforschung 01.11.1989
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Summary:The preparations and characterizations of compounds SCl MF ~ (M = As, Sb) are reported. They are yellowish hydrolysable solids, with a strong tendency towards symmetrization in solution. The mass spectra data indicate the formation of SCl on thermolysis. The series of SCl -cations (n = 0—3) is now complete, and a comprehensive discussion of the spectroscopic data is given.
ISSN:0932-0776
1865-7117
DOI:10.1515/znb-1989-1102