Über die Reaktion von CF3OCI mit Lewis-Säuren und Br2 und I2 / Reaction of CF3OCI with Lewis Acids and with Br2 and I2

The reactions of CF OCl with SbX (X = F, Cl) and AsF at 195 K yield the adducts CF OCl · SbX and CF OCl · AsF respectively. At 213 K CF OCI · SbCl forms SbCl F, Cl and OCF , while compounds CF OCl · MF (M = As, Sb) slowly decompose giving ClF, OCF and mixed M(V) halides. The formation of IF , OCF an...

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Published inZeitschrift für Naturforschung. B, A journal of chemical sciences Vol. 50; no. 8; pp. 1277 - 1280
Main Authors Minkwitz, Rolf, Konikowski, Detlef
Format Journal Article
LanguageEnglish
Published Verlag der Zeitschrift für Naturforschung 01.08.1995
Subjects
NMR Spectra
Trifluormethyl Hypochlorite Arsene Pentafluoride Adduct
Trifluoromethyl Hypochlorite Antimony Pentachloride and Pentafluoride Adduct
Vibrational Spectra
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Summary:The reactions of CF OCl with SbX (X = F, Cl) and AsF at 195 K yield the adducts CF OCl · SbX and CF OCl · AsF respectively. At 213 K CF OCI · SbCl forms SbCl F, Cl and OCF , while compounds CF OCl · MF (M = As, Sb) slowly decompose giving ClF, OCF and mixed M(V) halides. The formation of IF , OCF and Cl in the oxidative fluorination of I with CF OCl at 293 K is described. Br reacts with CF OCl to give BrF under similar conditions.
ISSN:0932-0776
1865-7117
DOI:10.1515/znb-1995-0824