Inside Cover: Controlling the Product Platform of Carbon Dioxide Reduction: Adaptive Catalytic Hydrosilylation of CO2 Using a Molecular Cobalt(II) Triazine Complex (Angew. Chem. Int. Ed. 36/2020)

Organometallic treasure hunt A molecular cobalt catalyst “navigates” the CO2 reduction with phenylsilanes to arrive at each product level individually with high selectivity and activity. This demonstrates the possibility of developing adaptive catalytic systems for the use of carbon dioxide as raw m...

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Bibliographic Details
Published inAngewandte Chemie International Edition Vol. 59; no. 36; p. 15270
Main Authors Cramer, Hanna H., Chatterjee, Basujit, Weyhermüller, Thomas, Werlé, Christophe, Leitner, Walter
Format Journal Article
LanguageEnglish
Published 01.09.2020
Subjects
CO2 reduction
cobalt catalysts
homogeneous catalysis
hydrosilylation
pincer ligands
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Summary:Organometallic treasure hunt A molecular cobalt catalyst “navigates” the CO2 reduction with phenylsilanes to arrive at each product level individually with high selectivity and activity. This demonstrates the possibility of developing adaptive catalytic systems for the use of carbon dioxide as raw material for chemicals or energy carriers, as detailed by C. Werlé, W. Leitner et al. in their Research Article on page 15674.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.202010500