Phase Equilibria and Interaction Between the CsCl–PbCl2–PbO System Components

Thermal analysis was applied to determine liquidus temperatures in the CsCl–PbCl –PbO system, with the PbO concentration ranging from 0 to 20 mol%. The temperature dependence of the PbO solubility in the CsCl–PbCl eutectic melt was studied, and the thermodynamic parameters of the PbO dissolution wer...

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Bibliographic Details
Published inZeitschrift für Naturforschung. A, A journal of physical sciences Vol. 70; no. 10; pp. 851 - 858
Main Authors Arkhipov, Pavel A., Zakiryanova, Irina D., Kholkina, Anna S., Bausheva, Alexandra V., Khudorozhkova, Anastasia O.
Format Journal Article
LanguageEnglish
Published De Gruyter 01.10.2015
Subjects
Lead Oxide
Lead Oxychloride
Liquidus Temperature
Raman Spectroscopy
Solubility
Thermal Analysis
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Summary:Thermal analysis was applied to determine liquidus temperatures in the CsCl–PbCl –PbO system, with the PbO concentration ranging from 0 to 20 mol%. The temperature dependence of the PbO solubility in the CsCl–PbCl eutectic melt was studied, and the thermodynamic parameters of the PbO dissolution were calculated. The type, morphology, and composition of oxychloride ionic groupings in the melt were determined using Raman spectroscopy.
ISSN:0932-0784
1865-7109
DOI:10.1515/zna-2015-0273