First total synthesis of (+/-)-abieta-8, 11, 13-trien-7 beta-ol

The first total synthesis of (+/-)-abieta-8, 11, 13-trien-7beta-ol (7) was accomplished via a strategy of AC --> ABC, in which the reduction of the ketone 6 with LiAlH4 gave exclusively the title compound.

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Bibliographic Details
Published inChinese chemical letters Vol. 14; no. 5; pp. 441 - 442
Main Authors Zhang, CL, Bie, PY, Peng, XJ, Yang, Y, Pan, XF
Format Journal Article
LanguageEnglish
Published NEW YORK Elsevier 01.05.2003
Department of Chemistry, National Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
SALVIA-MILTIORRHIZA
METHYL-ETHER
diterpene
DITERPENOIDS
total synthesis
(+/-)-abieta-8, 11, 13-trien-7 beta-ol
STEREOSELECTIVE SYNTHESIS
Total synthesis,(±)-abieta-8,11,13-trien-7β-ol,diterpene
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Summary:The first total synthesis of (+/-)-abieta-8, 11, 13-trien-7beta-ol (7) was accomplished via a strategy of AC --> ABC, in which the reduction of the ketone 6 with LiAlH4 gave exclusively the title compound.
ISSN:1001-8417
1878-5964