Synthesis and characterization of some unsymmetrically-substituted mesoporphyrinic mono-hydroxyphenyl complexes of copper(II)

• Published in: Polish journal of chemistry Vol. 82; no. 3; pp. 509 - 521
• Main Authors: Boscencu, R., Socoteanu, R., Oliveira, A. Sousa, Ferreira, L. F. Vieira, Nacea, V., Patrinoiu, G.
• Format: Journal Article
• Language: English
• Published: WARSAW Polish Chemical Soc 01.03.2008
• Subjects: Chemistry; Chemistry, Multidisciplinary; Physical Sciences; Science & Technology; sensitizers for photodynamic therapy; molecular absorption coefficients; SQUARYLIUM CYANINE DYES; PHOTODYNAMIC THERAPY; PORPHYRINS; PHOTOSENSITIZERS; MECHANISMS; Cu(II) porphyrin complexes; LUMINESCENCE; FTIR; SINGLET OXYGEN GENERATION; STRUCTURAL MODIFICATIONS; asymmetric porphyrins; DERIVATIVES; EFFICIENCY; EPR and UV-Vis spectroscopy

A series of four copper(II) complexes, with porphyrinic ligands: 5,10,15,20-tetrakis- phenyl-21,23-H-porphine (TPP), 5-(4-hydroxyphenyl)-10,15,20-tri-phenyl-21,23-H-porphine (TPPOHp), 5-(3-hydroxyphenyl)-10,15,20-tri-phenyl-21,23-H-porphine (TPPOHm), 5-(2-hydroxyphenyl)-10,15,20-tri-phenyl-21,23-H-p...