Synthesis, crystal structures and antibacterial activity of two copper(II) complexes derived from 2,4-dibromo-6-[(3-cyclohexylaminopropylimino)methyl]phenol

Two Schiff base copper(II) complexes, [Cu(2)L(2)(mu(2)-1,1-N(3))(2)] (1) and [Cu(HL)(2)(NCS)(2)]center dot 2CH(3)OH (2) (HL = 2,4-dibromo-6-[(3-cyclohexylaminopropylimino)methyl]phenol), were synthesized and characterized by elemental analyses, IR spectra, and single crystal X-ray diffraction. Each...

Full description

Saved in:
Bibliographic Details
Published inPolish journal of chemistry Vol. 82; no. 7; pp. 1353 - 1359
Main Author Wang, C. -Y.
Format Journal Article
LanguageEnglish
Published WARSAW Polish Chemical Soc 01.07.2008
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
Schiff base
synthesis
antibacterial activity
copper complex
S-BENZYLDITHIOCARBAZATE
LIGANDS
SCHIFF-BASES
X-RAY-STRUCTURE
crystal structure
PAIR
Online AccessGet more information

Cover

More Information
Summary:Two Schiff base copper(II) complexes, [Cu(2)L(2)(mu(2)-1,1-N(3))(2)] (1) and [Cu(HL)(2)(NCS)(2)]center dot 2CH(3)OH (2) (HL = 2,4-dibromo-6-[(3-cyclohexylaminopropylimino)methyl]phenol), were synthesized and characterized by elemental analyses, IR spectra, and single crystal X-ray diffraction. Each Cu atom in the end-on azido-bridged dinuclear centrosymmetric complex (1) is five-coordinate in a square pyramidal coordination. The Cu atom in the mononuclear centrosymmetric complex (2) is six-coordinate in an octahedral coordination. The Schiff base ligand and the two complexes showed excellent antibacterial activity.
ISSN:0137-5083