Two step synthesis of 3,7,7-trimethyl-1,3,5-cycloheptatriene from Delta(3)-carene

3,7,7-trimethyl-1,3,5-cycloheptatriene was obtained in 74% overall yield when adducts from ene reaction between Delta(3)-carene and N-sulphinyl arenesulphonamides are reacted with hexamethyl disilazane at 80 degrees C.

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Bibliographic Details
Published inPhosphorus and sulfur and the related elements Vol. 101; no. 1-4; pp. 287 - 289
Main Authors Deleris, G, Gadras, A, Dunogues, J
Format Journal Article
LanguageEnglish
Published READING Taylor & Francis 01.04.1995
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Physical Sciences
Science & Technology
ene reaction
Delta-3 carene
ALKYLATION
N-sulphinyl arenesulphonamides
hexamethyl disilazane
ENE-REACTION
CYCLOHEPTATRIENE
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Summary:3,7,7-trimethyl-1,3,5-cycloheptatriene was obtained in 74% overall yield when adducts from ene reaction between Delta(3)-carene and N-sulphinyl arenesulphonamides are reacted with hexamethyl disilazane at 80 degrees C.
ISSN:0308-664X
DOI:10.1080/10426509508042529