Reactivity of the lithium salt of 4H-cyclopenta[2,1-b : 3,4-b ']dithiophene

The regioselectivity in reactions of the lithium salt of 4H-cyclopenta[2,1-b:3,4-b']dithiophene with various electrophilic agents [SiMe3Cl, SnMe3Cl, D2O, Re(CO)(5)Br] is discussed in terms of the charge and orbital control concepts.

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Bibliographic Details
Published inRussian journal of general chemistry Vol. 71; no. 11; pp. 1751 - 1753
Main Authors Kisun'ko, DA, Zabalov, MV, Myshakin, EM, Oprunenko, YF, Lemenovskii, DA
Format Journal Article
LanguageEnglish
Published NEW YORK Springer Nature 01.11.2001
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
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Summary:The regioselectivity in reactions of the lithium salt of 4H-cyclopenta[2,1-b:3,4-b']dithiophene with various electrophilic agents [SiMe3Cl, SnMe3Cl, D2O, Re(CO)(5)Br] is discussed in terms of the charge and orbital control concepts.
ISSN:1070-3632
DOI:10.1023/A:1013994425157