Iridium-catalyzed triple C(sp(3))-H borylations: construction of triborylated sp(3)-carbon centers

An unprecedented catalytic C(sp(3))-H triborylation at a single carbon was developed with the assistance of a nitrogen directing group.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 49; no. 49; pp. 5601 - 5603
Main Authors Mita, Tsuyoshi, Ikeda, Yuto, Michigami, Kenichi, Sato, Yoshihiro
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 23.05.2013
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
TRANSFORMATION
REAGENTS
CO2
REGIOSPECIFIC FUNCTIONALIZATION
CARBOXYLATION
PINACOLBORANE
CARBON-DIOXIDE
C-H BONDS
METHANETRIBORONIC ESTERS
ALKANES
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Summary:An unprecedented catalytic C(sp(3))-H triborylation at a single carbon was developed with the assistance of a nitrogen directing group.
Bibliography:KAKEN
ISSN:1359-7345
DOI:10.1039/c3cc42675k