Microwave-assisted chemoselective cleavage of oximes to their corresponding carbonyl compounds using 1,3-dichloro-5,5-dimethylhydantoin (DCDMH) as a new deoximating reagent

In the presence of alkene and alcohol, oximes are converted into their parent carbonyl compounds in good yields when treated with 1,3-dichloro-5,5-dimethylhydantoin (DCDMH) (1), under microwave irradiation. The simple work-up minimizes loss of products.

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Bibliographic Details
Published inSynthesis (Stuttgart) no. 12; pp. 1929 - 1931
Main Authors Khazaei, A, Manesh, AA
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 01.08.2005
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
ketone
selective
FACILE REGENERATION
aldehyde
oxime
EFFICIENT
microwave
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Summary:In the presence of alkene and alcohol, oximes are converted into their parent carbonyl compounds in good yields when treated with 1,3-dichloro-5,5-dimethylhydantoin (DCDMH) (1), under microwave irradiation. The simple work-up minimizes loss of products.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-2005-869901