Synthesis, Characterization and Reactivity of Bis(4-tert-butylphenolato)dichlorotin(IV)

The bis(4-tert-butylphenolato)dichlorotin(IV) complex of composition SnCl(2)(OC(6)H(4)Bu(t)-4)(2) (1) has been synthesized by the reaction of tin tetrachloride with bimolar amount of 4-t-butylphenol in benzene under reflux and characterized by elemental analyses, molar conductance measurements, mole...

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Bibliographic Details
Published inPolish journal of chemistry Vol. 83; no. 9; pp. 1537 - 1545
Main Authors Chaudhry, S. C., Bandna, Kumari, Bhatt, S. S., Sharma, Neeraj
Format Journal Article
LanguageEnglish
Published WARSAW Polish Chemical Soc 01.09.2009
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
VIBRATIONAL SPECTRA
IMIDAZOLE COMPLEXES
INFRA-RED SPECTRA
METAL CENTERS
LIGATION
acceptor properties
tin(IV) compound
thermal studies
RAY CRYSTAL-STRUCTURES
SCHIFF-BASE
spectral properties
LIGAND
BENZIMIDAZOLES
4-t-butylphenol
DERIVATIVES
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Summary:The bis(4-tert-butylphenolato)dichlorotin(IV) complex of composition SnCl(2)(OC(6)H(4)Bu(t)-4)(2) (1) has been synthesized by the reaction of tin tetrachloride with bimolar amount of 4-t-butylphenol in benzene under reflux and characterized by elemental analyses, molar conductance measurements, molecular weight determination, IR, (1)H, (13)C NMR and FAB mass spectral techniques. Thermal behaviour of the complex has been investigated using TG-DTA technique. Lewis acid character of (1) has been explored by isolating its addition compounds with some nitrogeneous bases viz. diethylamine, triethylamine, imidazole, benzimidazole (L); 2,2'-bipyridyl, and 1,10-phenanthroline (B) of composition, SnCl(2)(OC(6)H(4)Bu(t)-4)(2)center dot 2L and SnCl(2)(OC(6)H(4)Bu(t)-4)(2)center dot B, characterized by physicochemical and IR spectral studies.
ISSN:0137-5083